A unique and comprehensive overview of this hot topic, reflecting the many recent advances and developments.
Volume 1 describes coordination chemistry of iron complexes, ligand effects and highlights spectroscopic techniques and theoretical methods used to characterize iron complexes under catalytic conditions, while also including a section on biomimetic iron catalysis. Volume 2 then goes on to summarize important applications of iron catalysts in organic synthesis, covering reduction and oxidation reactions, cross–coupling and C–H activation reactions, nucleophilic substitution, cycloisomerization, radical iron chemistry, and iron–catalyzed polymerizations and oligomerizations.
Edited by one of the leaders in the field, this timely handbook in two volumes is a must–have for all researchers in academia and industry working in the field of catalysis, organic synthesis, inorganic and organometallic chemistry, spectroscopy, and physical and theoretical chemistry.
Volume 1 describes coordination chemistry of iron complexes, ligand effects and highlights spectroscopic techniques and theoretical methods used to characterize iron complexes under catalytic conditions, while also including a section on biomimetic iron catalysis. Volume 2 then goes on to summarize important applications of iron catalysts in organic synthesis, covering reduction and oxidation reactions, cross–coupling and C–H activation reactions, nucleophilic substitution, cycloisomerization, radical iron chemistry, and iron–catalyzed polymerizations and oligomerizations.
Edited by one of the leaders in the field, this timely handbook in two volumes is a must–have for all researchers in academia and industry working in the field of catalysis, organic synthesis, inorganic and organometallic chemistry, spectroscopy, and physical and theoretical chemistry.
Table of Contents
PrefaceVOLUME 1: COORDINATION CHEMISTRY, LIGAND EFFECTS, BIOMIMETIC CATALYSIS AND APPLIED SPECTROSCOPY
1. Coordination Chemistry of Iron and the Role of "Non–Innocent" Ligands in Iron Catalysis
2 [Fe]–Hydrogenase, [FeFe]–Hydrogenase, [FeNi]–Hydrogenase Activities
3 Non–Heme–Fe–Complexes in Catalysis
4 Heme–Type–Fe–Complexes in Catalysis
5. Mößbauer Spectroscopy
6. X–Ray Spectroscopy
7. EPR–Spectroscopy
8. Spectroelectrochemistry
9. UV–Vis–Flash–Photolysis–Dynamic IR–Spectroscopy
10. NMR–Spectroscopy (Diamagnetic and Paramagnetic)
11. SQUIDD, Magnetometry
12. DFT–Methodology
13. ab–initio–Methodology
14. Applied Theory – in–Silico–Spectroscopy
VOLUME 2: APPLIED IRON CATALYSIS
15. Reduction of Carbonyl and Heterocarbonyl Groups
16. Reduction of CO2
17. Fe–catalyzed Reductive Transformations of Olefins/Alkynes
18. Oxidations of C,H– and C=C–Bonds
19. Oxidative Allylic Oxygenation and Amination
20. Oxidation of Heteroatoms (N, P and S)
21. Cross–Coupling
22. C–H Activation
23. Nucleophilic Substitution
24. Radical Iron Chemistry
25. Cycloisomerization
26. Fe–catalyzed Polymerizations and Oligomerizations
