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Electron Paramagnetic Resonance in Modern Carbon-Based Nanomaterials

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    Book

  • June 2018
  • Bentham Science Publishers Ltd
  • ID: 4590466

This volume presents information about several topics in the field of electron paramagnetic resonance (EPR) study of carbon-containing nanomaterials. It introduces the reader to an array of experimental and theoretical approaches for the analysis of paramagnetic centers (dangling bonds, interface defects, vacancies, and impurities) usually observed in modern carbon-containing materials such as nanographites, graphene, disordered onion-like carbon nanospheres (DOLCNS), single-walled carbon nanotubes (SWCNTs), multi-walled carbon nanotubes (MWCNT), graphene oxide (GO), reduced graphene oxide (rGO), nanodiamonds, silicon carbonitride (SiCN) and silicon carbide (SiC) based composites and thin films.

In particular, the book describes in detail:


  • The fundamentals of EPR spectroscopy and its application to the carbon-containing materials
  • The resolution of the EPR signals from different species in carbon materials
  • EPR characterization of spin dynamics in carbon nanomaterials
  • Magnetic properties of DWCNTs and MWCNTs polymer composites
  • EPR investigations on GO, rGO and CNTs with different chemical functionalities
  • EPR spectroscopy of semiconducting SWCNTs thin films and their transistors
  • In-situ EPR investigations of the oxygenation processes in coal and graphene materials
  • The two-temperature EPR measurement method applied to carbonaceous solids
  • Characterization of impurities in nanodiamonds and SiC nanomaterials and related size effects by CW and pulse EPR techniques
  • Application of multifrequency EPR to the study of paramagnetic defects in a-Si1-xCx:H thin films and a-SiCxNy based composites

This volume is a useful guide for researchers interested in the EPR study of paramagnetic centers in the carbon-containing thin films, nanomaterials, ceramics, etc. It is also a valuable teaching tool at graduate and postgraduate levels for advanced courses in analytical chemistry, applied sciences and spectroscopy.

Series Description:

This series brings reference works and monographs on topics related to analytical methods employing different modes of magnetic resonance spectroscopy. Contributions are written by eminent scholars. Volumes in this series are suitable for researchers and teachers involved in advanced courses in analytical techniques, applied sciences and condensed matter physics.

Table of Contents

Chapter 1 Fundamentals of Electron Paramagnetic Resonance in Modern Carbon-Based Materials

Chapter 2 Resolution of EPR Signals in Graphene-Based Materials From Few Layers To Nanographites

Chapter 3 Study of Electron Spin Lifetime of Conducting Carbon Nanomaterials

Chapter 4 EPR Spectroscopy On Double-Walled and Multi-Walled Carbon Nanotube Polymer Composites

Chapter 5 Impact of Point Defects On Graphene Oxide and Carbon Nanotubes: Study of Electron Paramagnetic Resonance Spectroscopy

Chapter 6 Electron Spin Resonance Spectroscopy of Single-Walled Carbon-Nanotube Thin-Films and Their Transistors

Chapter 7 Characterizing the Nature of Surface Radicals in Carbonbased Materials, Using Gas-Flow EPR Spectroscopy

Chapter 8 Application of the Two-Temperature EPR Measurement Method To Carbonaceous Solids

Chapter 9 Paramagnetic Defects and Impurities in Nanodiamonds As Studied by Multi-Frequency Cw and Pulse EPR Methods

Chapter 10 EPR and FMR of SiCn Ceramics and SiCn Magnetic Derivatives

Chapter 11 CW and Pulse EPR Study of Paramagnetic Centers in Silicon Carbide Nanomaterials

Chapter 12 Size-Dependent Effects in Silicon Carbide and Diamond Nanomaterials As Studied by CW and Pulse EPR Methods

Chapter 13 Paramagnetic Defects in Amorphous Hydrogenated Silicon Carbide and Silicon Carbonitride Films

Author

  • Dariya Savchenko
  • Abdel Hadi Kassiba