Catalysis is an area of chemical sciences which has fascinated a wide range of academicians, researchers, chemical technologists and industries throughout the world. Progress in this field has been made owing to the thrust provided by this research and commercial interest. The field of catalysis is interdisciplinary by its nature, as it requires knowledge of organic synthesis, coordination and organometallic chemistry, reaction kinetics and mechanisms, stereochemical concepts and materials science. Fundamentals and Prospects of Catalysis highlight many important topics and sub-disciplines in catalysis by presenting 7 chapters on different but varied catalytic processes.
This volume presents the following topics:
- Organocatalytic Asymmetric Synthesis of Spiroacetals and Bridged Acetals
- Design and Development of Bimetallic Enantioselective Salen Co Catalysts for The Hydrolytic Kinetic Resolution of Terminal Epoxides
- Recent Trend in Asymmetric Heterogeneous Flow Catalysis
- Ball Milling: A Green Tool in Synthetic Organic Chemistry
- Recent Advances in the Developments of Enantioselective Electrophilic Fluorination Reactions via Organocatalysis
- Green and Sustainable Biocatalytic Routes to Prepare Biobased Polyols as Precursors for Polyurethanes with Comparison of Existing Biobased Polyol Technology
- Polymers Used as Catalysts
Table of Contents
Chapter 1 Organocatalytic Asymmetric Synthesis of Spiroacetals and Bridged Acetals
- Introduction
- Review of Investigation Results: Organocatalytic Asymmetric
- Synthesis of Spiroketals
- (R)-2,2-Diphenyl-1,7-Dioxaspiro[5.5]Undecane (14)
- General Procedure[7]
- (S)-1,6-Dioxaspiro[4.4]Nonane (19)
- General Procedure [8]
- 1-Phenyl-2-((2R,5S)-1,6-Dioxaspiro[4.4]Nonan-2-Yl)Ethan-1-One (24)
- General Procedure [9]
- (S)-3H,3'H-2,2'-Spirobi[Benzofuran]-3-One (29)
- General Procedure [10]
- Review of Investigation Results: Organocatalytic Asymmetric
- Synthesis of Bridged Acetals
- 1-((1S,5S)-3-Methyl-2,8-Dioxabicyclo[3.3.1]Non-3-En-4-Yl)Ethan-1-One (32)
- General Procedure [11]
- General Procedure [12]
- General Procedure [13]
- Conclusion
- Consent for Publication
- Conflict of Interest
- Acknowledgements
- References
Chapter 2 Design and Development of Bimetallic Enantioselective Salen Co Catalysts for the Hydrolytic Kinetic Resolution Of Terminal Epoxides
- Background and Motivation
- Kinetic Resolution and Jacobsen HKR Method
- Bi- and Multimetalic Hydrolytic Kinetic Resolution
- Conclusion and Prospects
- Consent for Publication
- Conflict of Interest
- Acknowledgements
- References
Chapter 3 Recent Trends in Asymmetric Heterogeneous Flow Catalysis
- Introduction
- Megha Balha and Subhas Chandra Pan
- Santosh Singh Thakur, Deepak Patel, Nidhi Nirmalkar, Kiran Thakur and Goutam
- Kumar Patra
- Rama Jaiswal, Melad Shaikh and Kalluri V.S. Ranganath
- Synthesis of Benzofused Acetals (35) and (36)
- ((2′R,3S,5′S)-1-Benzyl-5′H-Spiro[Indoline3,4′ [2, 5]Methanobenzo[D] [1, 3] Dioxepin]--One) (39)
- Asymmetric Hydrogenation
- Asymmetric Arylation
- Alkylation
- Asymmetric Aldol Reactions
- Asymmetric Michael Reactions
- Asymmetric Carbene Transfer Reactions
- Other Asymmetric Reactions in a Continuous Flow
- Conclusion and Perspectives
- Consent for Publication
- Conflict of Interest
- Acknowledgements
- References
Chapter 4 Ball Milling: a Green Tool in Synthetic Organic Chemistry
- Introduction of All Milling
- General Introduction
- Major Reaction Parameter in Ball Milling
- Principles of Ball Milling
- Organic Reactions Under Ball Milling Conditions
- Carbon-Carbon and Carbon-Heteroatom Bond Formation Via Michael Addition
- Condensation Reactions
- Elementary Condensation Reactions
- Cyclocondensation-Heterocyclizataion Leading to Heterocyclic Compounds
- Cyclocondensation Reactions
- Condensation Cycloaddition Reactions
- Cyclization Addition Via Click Reactions
- Miscellaneous Reactions
- Carbon- Heteroatom Bond Formation Via Substitution Reactions
- Carbon-Heteroatom Bond Formation Via Additionfollowed by Cycloaddition
- Reactions
- Coupling Reactions
- Carbon-Carbon and Carbon-Heteroatom Bond Formation Via Alkylation Reactions
- Carbon-Nitrogen Bond Formation Via Carbon-Hydrogen Bond Activation
- Transesterification Reactions Under Ball Milling Conditions
- Oxidation and Reduction Reactions
- Conclusion
- Consent for Publication
- Conflict of Interest
- Acknowledgements
- References
Chapter 5 Recent Advances in the Developments of Enantioselective Electrophilic Fluorination Reactions Via Organocatalysis
- Introduction
- An Overview of Asymmetric Organocatalysis
- Organocatalytic Enantioselective Electrophilic Fluorination
- Reactions
- Primary Amine Catalyzed Enantioselective Electrophilic Fluorination
- Secondary Amine Catalyzed Enantioselective Electrophilic Fluorination
- Tertiary Amine Catalyzed Enantioselective Electrophilic Fluorination
- Subhash Banerjee, Geetika Patel and Medha Kiran Patel
- Kavita Jain and Kalpataru Das
- Enantioselective Electrophilic Fluorination Via Phase Transfer Catalysis (PTC)
- Enantioselective Electrophilic Fluorination Via Hydrogen Bonding Catalysis
- Concluding Remarks
- Consent for Publication
- Conflict of Interest
- Acknowledgements
- References
Chapter 6 A Green and Sustainable Biocatalytic Routes to Prepare Biobased Polyols as a Precursor for Polyurethanes as Compared To Existing Biobased Polyol Technology
- Introduction
- Background
- Current Biobased Polyol Technology
- Status of the Existing Bio-Based Technology
- Drawbacks of Exiting Polyol Technology
- Preparation of Biocatalysed Polyols
- Scheme to Prepare Polyol Polyesters
- Structure of Expected Polyol Polyesters
- Biobased Building Blocks for Polyol Polyester Synthesis
- Advantage of Biocatlysis
- Significance of Biocatalysis
- Consent for Publication
- Conflict of Interest
- Acknowledgements
- References
Chapter 7 Polymers Used as Catalyst
- Introduction
- Catalysis by Soluble Linear Polymer
- Soluble Polymer-Supported Organocatalyst
- Catalysis by Ion Exchange Resins
- Olefin Oligomerization
- Etherification Via Alcohol Addition to Olefins
- Carbon-Carbon Coupling Reactions Catalyzed by Nanoparticles Supported on Commercial
- Ion-Exchange Resins
- Polymer Resins as Nanoreactors for the Synthesis of Nanoparticles and Their Catalytic
- Application in C-C Coupling
- Catalysts Containing Free Metal
- Catalysts Containing the Metal in the Form of a Compound, Ion, or Complex
- Recent Advances in Polymer-Supported Pd (Psp) Complexes for Sonogashira Coupling
- Reactions (Scr)
- Polymeric Phase-Transfer Catalysts and Nucleophilically Active Polymers
- Polymer Modification and Functionalization
- Consent for Publication
- Conflict of Interest
- Acknowledgements
- References
- Bhaskar Sharma, Hema Tandon, Pathik Maji and Arti Shrivastava
- Arti Srivastava, Bhaskar Sharma and Pratibha Mandal
- Subject Index
Companies Mentioned
- Goutam Kumar Patra
- Santosh Singh Thakur
