Primary reference on polymeric corrosion inhibitors for researchers and professionals in the chemical and petrochemical industries
Polymeric Corrosion Inhibitors for Greening the Chemical and Petrochemical Industry provides an extensive overview of polymeric corrosion inhibitors for chemical and petrochemical industry - from design, synthesis, and characterization - to applications. The text discusses the different media in which corrosion is observed and enables readers to minimize/prevent pipes and other plant systems’ failures by adequately dealing with corrosion.
Considering the high importance of corrosion inhibitors development for the chemical and petrochemical industries, this book aims to provide fundamental and current practice with comprehensive coverage of the recent advancements of green polymeric corrosion inhibitors that could be used. The text systematically presents fundamentals, up-to-date development, and industrial applications of polymeric corrosion inhibitors.
In Polymeric Corrosion Inhibitors for Greening the Chemical and Petrochemical Industry, readers can expect to find specific information on: - Water- and oil-soluble polymeric corrosion inhibitors, plus polymeric corrosion inhibitors for acid, CO2 (sweet), H2S (sour), cooling water, and basic media - Polymers as kinetic hydrate inhibitors, high-temperature polymeric corrosion inhibitors, and polymeric inhibitors for microbiologically influenced corrosion - Surface characterization techniques in corrosion inhibition research and guidelines for designing corrosion inhibitors for oil and gas production - The impact of corrosion inhibitors as green polymeric materials and what they mean for the future of the field
Polymeric Corrosion Inhibitors for Greening the Chemical and Petrochemical Industry is a primary reference for researchers and professionals in the material science, chemistry and electrochemistry, chemical, mechanical, and metallurgical engineering industries who wish to counter the economic and environmental consequences of corrosion in various plant systems.
Table of Contents
Preface xv
Acknowledgments xvii
About the Editors xix
1 Green Polymeric Corrosion Inhibitors: Design, Synthesis, and Characterization 1
Dheeraj S. Chauhan, Mumtaz A. Quraishi, Hussein Al-Qahtani, and Mohammad A. Jafar Mazumder
1.1 Introduction 1
1.2 Corrosion and Its Economic Significance 2
1.3 Corrosion Inhibitors 2
1.4 Polysaccharides as Corrosion Inhibitors 4
1.5 Proteins and Polyamino Acids as Corrosion Inhibitors 7
1.6 Chemically Modified Biopolymers as Corrosion Inhibitors 10
1.7 Biopolymer Nanoparticles as Corrosion Inhibitors 13
1.8 Biopolymer Composites as Corrosion Inhibitors 13
1.9 Adsorption and Protection Mechanism of Biopolymers on the Metal Surface 14
1.10 Conclusions and Prospects 16
2 Natural Polymers and Their Derivatives as Corrosion Inhibitors for the Oil and Gas Industry 23
Ali F.S.A. Rahiman, Menaka Ramanathan, and Sethumanickam Subhashini
2.1 Introduction 23
2.2 Reliable Methods for the Study of Polymeric Corrosion Inhibitors 24
2.3 Natural Polymeric Corrosion Inhibitors 26
2.4 Mechanism for Natural Polymeric Corrosion Inhibition 41
2.5 Conclusion and Outtake for FutureWork 42
3 Current Applications of Carbohydrates as Green Corrosion Inhibitors for the Oil and Gas Industry 55
Ruby Aslam, Mohammad Mobin, Saman Zehra, and Jeenat Aslam
3.1 Introduction 55
3.2 Carbohydrate Polymers: A Sustainable Alternatives 57
3.3 Conclusion 73
4 Poly(Amino Acid) Corrosion Inhibitors 79
Brahim El Ibrahimi and Nada K. Sebbar
4.1 Introduction 79
4.2 Poly(Amino Acid) Homopolymers as Corrosion Inhibitors 81
4.3 Modified Poly(Amino Acid) and Poly(Amino Acid) Copolymers as Corrosion Inhibitors 84
4.4 Poly(Amino Acid) Composite Polymers as Corrosion Inhibitors 89
4.5 Conclusion 92
5 Water-Soluble Polymeric Corrosion Inhibitors 97
Lipiar K.M.O. Goni, Mohammad A. Jafar Mazumder, Shaikh A. Ali, and Dheeraj S. Chauhan
5.1 Introduction 97
5.2 Polymers asWater-Soluble Corrosion Inhibitors 98
5.3 Industrial Applications ofWater-Soluble Polymeric Corrosion Inhibitors 113
5.4 Conclusions 116
6 High-Temperature Polymeric Corrosion Inhibitors 125
Jiyaul Haque, Mumtaz A. Quraishi, and Wan M.N.B. Wan Nik
6.1 Introduction 125
6.2 Polymer as Corrosion Inhibitor for High-Temperature Oil-Well Acidization 126
6.3 Polymer as Corrosion Inhibitor for High-Temperature Sour and Sweet Environment 131
6.4 Polymer as Corrosion Inhibitor for High-Temperature Naphthenic Acids Environment 133
6.5 Computational Studies of Polymeric Corrosion Inhibitors 134
6.6 Conclusions and Outlook 138
7 Polyurethane Corrosion Inhibitor 143
Mohammad M. Rahman
7.1 Introduction 143
7.2 Polyurethane (PU) 144
7.3 Polymer as an Inhibitor 147
7.4 PU as Corrosion Inhibitor (PUCI) 148
7.5 Mechanism of PUCI Inhibition 154
7.6 Conclusions and Perspectives 155
8 Dual-Purpose Kinetic Hydrate and Corrosion Inhibitors 161
Muhammad I. Ulhaq
8.1 Introduction 161
8.2 Corrosion Inhibitors (CIs) 164
8.3 Kinetic Hydrate Inhibitors (KHIs) 167
8.4 Dual-Purpose Chemicals 170
8.5 Dual-Purpose Corrosion Inhibitor and KHIs (GHCIs) 170
8.6 Conclusion and Future Prospects 180
9 Polymers as Corrosion Inhibitors for Sweet Environment 193
Dheeraj S. Chauhan, Vandana Srivastava, Yuanhua Lin, and Mumtaz A. Quraishi
9.1 Introduction 193
9.2 An Overview of Corrosion 194
9.3 Sweet Corrosion 195
9.4 Polymers as Sweet CI 205
9.5 Computational Modeling of Polymeric Inhibitors for Sweet Corrosion 212
9.6 Mechanism of Adsorption and Inhibition 214
9.7 Conclusions and Prospects 215
10 Green Polymeric Inhibitors for Corrosion of Metals in Alkaline Media 221
Refat M. Hassan (El-Moushy)
10.1 Definitions of Corrosion 221
10.2 Main Reasons for Metals Corrosion 222
10.3 Theories of Corrosion 222
10.4 General Types of Corrosions 224
10.5 Corrosion Reactions of Al in Alkaline Media 229
10.6 Techniques for Prevention and Protection ofMetals from Corrosion 230
10.7 Applied Methodologies for Measurements of Corrosion Rates 235
10.8 Factors Affecting the Corrosion Process 236
10.9 Conclusion 246
11 Polymeric Corrosion Inhibitors for Acid Media 257
Nurudeen A. Odewunmi, Mohammad A. Jafar Mazumder, and Shaikh A. Ali
11.1 Background 257
11.2 Outward and Inward Acid Corrosion 258
11.3 Organic and Inorganic Corrosion Inhibitor in Acid Media 259
11.4 Natural Polymeric Materials 262
11.5 Essential Oils 262
11.6 Carbohydrates (CHO) 263
11.7 Natural Proteins 272
11.8 Synthetic Polymeric Materials 275
11.9 Conclusion 289
12 Polymeric Corrosion Inhibitors for Microbiologically Influenced Corrosion 305
Chaitanya Kumar, Mohan Yama, and Jaya Rawat
12.1 Introduction to Microbiologically Influenced Corrosion (MIC) 305
12.2 Microbes in MIC 306
12.3 Biofilms 307
12.4 MIC Issues in Industry: Oil and Gas 309
12.5 Corrosion Inhibitors for MIC 310
12.6 Polymeric Corrosion Inhibitors 312
12.7 Conclusions 317
13 Smart Polymers Coating for Upstream Oil and Gas Industry to Slow Down the Corrosion 331
Rabia Nazar, Umer Mehmood, Hassan Ahmed, Aimen Imran, and Syed A. Raza
13.1 Introduction 331
13.2 Mechanism of Corrosion 334
13.3 Kinds of Corrosion in Industry 337
13.4 Conventional Corrosion Prevention Methods 341
13.5 Smart Coatings 343
13.6 Conclusion 349
14 Surface Characterization Techniques in Corrosion Inhibition Research 353
Ambrish Singh, Kashif R. Ansari, Shivani Singh, Mumtaz A. Quraishi, and Yuanhua Lin
14.1 Introduction 353
14.2 Method ofWeight Loss 354
14.3 Parameters of Adsorption 357
14.4 Electrochemical Techniques 360
14.5 Surface Analytical Techniques 367
14.6 Conclusion 378
15 Guidelines for Designing Corrosion Inhibitors for Oil and Gas Production 383
Nayef M. Alanazi and Muhammad I. Ulhaq
15.1 Introduction 383
15.2 Classification of Corrosion 384
15.3 Corrosion Inhibitors 385
15.4 Corrosion Inhibitor Management 393
15.5 Safety on Designing Corrosion Inhibitor 399
15.6 Conclusions 399
Acknowledgment 400
List of Abbreviations 400
References 400
Index 407
