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Hydrotalcite-Based Materials: Synthesis, Characterization and Application

  • Book

  • August 2024
  • Bentham Science Publishers Ltd
  • ID: 5993915
Hydrotalcite-based materials, characterized by their unique composition are integral to diverse applications in heterogeneous catalysis and beyond. Renowned for their catalytic prowess, these compounds serve as versatile bases for organic reactions, support structures for metal catalysts, and facilitators in organic transformations and water treatment. This comprehensive book introduces readers to hydrotalcite-like compounds, with ten chapters exploring variations in metal ion ratios and interlayer anions, and their impact on properties crucial for industrial applications (ranging from industrial catalysis to medicine).

Key features:

  • Detailed exploration of hydrotalcite and hydrotalcite-like compounds
  • Recent trends and applications in industrial catalysis, organic synthesis, and environmental remediation
  • Hydrotalcite synthesis including methods like coprecipitation, sol-gel processing, and advanced techniques
  • Contributions from leading researchers in the field with references
  • Comprehensive overview for each topic suitable for both academics and industry professionals
  • With its exhaustive coverage of hydrotalcite-based materials and their multifaceted applications, this book promises to be an indispensable resource for anyone who wants to understand the utilization of hydrotalcites for advanced catalytic processes.

Readership:

  • Academics, chemistry students, professionals and apprentices in chemical engineering and synthesis.

Table of Contents

PREFACE
  • LIST OF CONTRIBUTORS
CHAPTER 1 HYDROTALCITE AND HYDROTALCITE-BASED MATERIALS
  • K Ganesh Kadiyala and Kadali Jagadeesh
  • 1. INTRODUCTION
  • 2. HISTORY AND MAIN FACTS ON HYDROTALCITE BASED MATERIALS
  • 2.1. Hydrotalcites Synthesis
  • 2.2. Hydrotalcites General Applications
  • 2.2.1. Hydrotalcites in Building Materials
  • 2.2.2. Hydrotalcites in Radioactive Waste Repository
  • 2.2.3. Hydrotalcites in Reinforced Concrete to inhibit the Corrosion
  • 2.2.4. Hydrotalcites in Cements and Mortars
  • 2.2.5. Hydrotalcites in Polymer Composites
  • 2.2.6. Hydrotalcites in Acid Neutralization
  • 3. WHY HYDROTALCITE ATTRACTED THE SCIENTIFIC COMMUNITIES
  • 4. NUMBER OF PUBLICATIONS INCREASED DAY BY DAY ON HYDROTALCITE-
  • BASED MATERIALS
  • 5. ENVIRONMENTAL FATE
  • 5.1. Hydrotalcite acts as a Photocatalyst for the Degradation of 2,4,6-Trichlorophenol
  • 5.2. Future Application of Hydrotalcite as Sorbents under Dynamic Flow Conditions.
  • 5.3. Hydrotalcite Colloidal Stability and Interactions with Uranium
  • 5.4. LDH in Chosen Environmental Applications
  • CONCLUSION
  • REFERENCES
CHAPTER 2 SYNTHESIS AND CHARACTERIZATION OF HYDROTALCITE-BASED
  • MATERIALS
  • Nishu Dhanda,Chetna Kumari, Diksha Bareth and Sudesh Kumar
  • 1. INTRODUCTION
  • 2. SYNTHESIS OF MAGNESIUM-ALUMINIUM HYDROTALCITE (MAH)
  • 2.1. Characterization of MgAl-hydrotalcite
  • 2.1.1. Analysis of the MgAl Hydrotalcite Composition in Chemicals
  • 2.1.2. XRD Analysis
  • 2.1.3. Fourier-transform Infrared Spectroscopy
  • 2.1.4. Zeta Analysis
  • 2.1.5. FE-SEM Observation
  • 3. NOVEL HYDROTALCITE-LIKE (CE AND LA) RARE EARTH SUBSTANCE
  • SYNTHESIS AND CHARACTER DEVELOPMENT
  • 3.1. Characterization
  • 3.1.1. SEM Observation
  • 3.1.2. XRD Patterns
  • 3.1.3. Raman Spectra
  • 4. SOME OTHER SYNTHESIS METHODS OF HYDROTALCITE-LIKE MATERIALS
  • 4.1. Synthesis of CuZnAl Hydrotalcite Co-Precipitation Technique
  • 4.2. Synthesis of CuMgAl by Co-Precipitation
  • 4.3. Mg-Al HT Synthesis by Titration Method
  • 5. APPLICATION OF HYDROTALCITE-BASED MATERIALS
  • CONCLUSION
  • ACKNOWLEDGEMENT
  • ABBREVIATIONS
  • REFERENCES
CHAPTER 3 DIVERGENT APPLICATIONS OF HYDROTALCITE-BASED MATERIALS
  • P C Sreeja, Rekha Sharma and Sapna Nehra
  • 1. INTRODUCTION
  • 2. STRUCTURE AND PROPERTIES OF HYDROTALCITE-BASED NANOMATERIALS
  • 2.1. Structure
  • 2.1.1. Particle Size
  • 2.1.2. Layered Structure
  • 2.1.3. Interlayer Region
  • 2.1.4. Intercalation
  • 2.1.5. Surface Modification
  • 2.1.6. Morphology
  • 2.1.7. Crystal Defects
  • 2.2. Properties
  • 2.2.1. Ion Exchange Capacity
  • 2.2.2. Catalytic Activity
  • 2.2.3. Adsorption Capability
  • 2.2.4. Thermal Stability
  • 2.2.5. Biocompatibility
  • 3. THE SYNTHESIS AND CHARACTERIZATION OF HYDROTALCITE-BASED
  • NANOMATERIALS
  • 3.1. Methods of Synthesis
  • 3.1.1. Co-precipitation Method
  • 3.1.2. Anion Exchange Method
  • 3.1.3. Intercalation Method
  • 3.1.4. Sol-gel Method
  • 3.1.5. Microwave-Assisted Synthesis
  • 3.2. Characterisation Techniques
  • 3.2.1. X-ray Diffraction (XRD)
  • 3.2.2. Scanning Electron Microscopy (SEM)
  • 3.2.3. Transmission Electron Microscopy (TEM)
  • 3.2.4. Fourier Transform Infrared Spectroscopy (FTIR)
  • 3.3.5. Thermal Analysis
  • 3.2.6. Surface Area and Pore Size Analysis
  • 3.2.7. Elemental Analysis
  • 4. DIVERGENT APPLICATIONS IN VARIOUS FIELDS
  • 4.1. Medical Applications
  • 4.1.1. Cytotoxicity
  • 4.1.2. Therapeutic Functions
  • 4.1.3. Diagnostic Functions
  • 4.2. Application in Water Purification
  • 4.2.1. Removal of Heavy Metals
  • 4.2.2. Removal of Dyes
  • 4.2.3. Removal of Microorganisms
  • 4.2.4. Removal of Other Impurities
  • 4.3. Carbon Dioxide Adsorption
  • 4.4. Porous Ceramics
  • 4.5. Deodorants
  • 4.6. Flame Retardant
  • CONCLUSION
  • ABBREVIATIONS
  • REFERENCES
CHAPTER 4 HYDROTALCITE-BASED MATERIALS IN NANOTECHNOLOGY
  • Tina Sharma,Mahipal Singh Sankhla and Archana Gautam
  • 1. INTRODUCTION
  • 1.1. A Brief Overview of Hydrotalcites and their Structure
  • 1.2. Importance of Hydrotalcite in Nanotechnology
  • 1.2.1. Nanocatalysis
  • 1.2.2. Drug Delivery Systems
  • 1.2.3. Environmental Remediation:
  • 1.2.4. Nanocomposites
  • 1.2.5. Energy Storage
  • 1.2.6. Gas Storage and Separation
  • 1.2.7. Sensor Technology
  • 1.2.8. Photocatalysis
  • 1.2.9. Biomedical Applications
  • 1.2.10. Water Treatment
  • 1.3. Synthetic Methods for Preparing Hydrotalcite
  • 1.3.1. Co-precipitation Method
  • 1.3.2. Anion exchange Method
  • 1.3.3. Sol-gel Method
  • 1.3.4. Hydrothermal Method
  • 1.3.5. Microwave-assisted Synthesis
  • 1.4. Synthetic Methods for Preparing Hydrotalcite
  • 1.4.1. Co-Precipitation Method
  • 1.4.2. Hydrothermal Synthesis
  • 1.4.3. Ion Exchange Method
  • 1.5. Applications of Hydrotalcite-based Materials in Nanotechnology
  • 1.5.1. Hydrotalcite-Supported Catalysts
  • 1.5.2. Selective Oxidation Reactions
  • 1.5.3. Carbon Dioxide Capture and Conversion
  • 1.5.4. Hydrotalcite-Based Drug Carriers
  • 1.5.5. Controlled Release of Drugs
  • 1.5.6. Enhanced Bioavailability of Drugs
  • 1.5.7. Hydrotalcite-Based Sensing
  • 1.5.8. Selective Detection of Various Analytes
  • 1.5.9. Applications in Environmental Monitoring
  • 1.5.10. Environmental Remediation
  • 1.6. Challenges and Future Directions
  • 1.6. Synthesis Control and Scalability
  • 1.6.1. Stability and Durability
  • 1.6.2. Surface Modification and Functionalization
  • 1.6.3. Controlled Release and Delivery
  • 1.6.4. Biocompatibility and Toxicity
  • 1.6.7. Cost-effectiveness
  • 1.7. Significance of Hydrotalcite-Based Materials in Nanotechnology
  • 1.7.1. Versatility and Tailorability
  • 1.7.2. Large Surface Area
  • 1.7.3. Ion-Exchange Properties
  • 1.7.4. Stability and Durability
  • 1.8. Future Directions in the Field of Hydrotalcite-based Nanotechnology
  • 1.9. Implications for Future Research and Development
  • 1.9.1. Advanced Synthesis Techniques
  • 1.9.2. Surface Modification Strategies
  • 1.9.3. Integration with Other Nanomaterials
  • 1.9.4. Biomedical Applications
  • 1.9.5. Sustainability and Green Approaches
  • 1.9.6. Multifunctional Applications
  • CONCLUSION
  • Summary of the Key Points
  • REFERENCES
CHAPTER 5 INDUSTRIAL APPLICATION OF HYDROTALCITE-BASED MATERIALS
  • Nibedita Banik and Navdeep Kaur
  • 1. INTRODUCTION TO HYDROTALCITE
  • 1.1. Definition and Structure of Hydrotalcite
  • 1.2. Synthesis Methods
  • 1.2.1. Co-precipitation Method
  • 1.2.2. Hydrothermal Method
  • 1.2.3. Ion-exchange Method
  • 1.2.4. Sol-Gel Method
  • 1.3. Properties and Characteristics
  • 1.3.1. Layered Structure
  • 1.3.2. Chemical Composition
  • 1.3.3. Ion Adsorption and Selectivity
  • 1.3.4. Ion Exchange Capacity
  • 1.3.5. pH-dependent Charge
  • 1.3.6. Thermal Stability
  • 1.3.7. Catalytic Activity
  • 1.3.8. Layer Swelling
  • 1.3.9. Structural Flexibility
  • 1.3.10. Biocompatibility
  • 1.3.11. Intercalation/Exfoliation
  • 2. CATALYST APPLICATIONS
  • 2.1. Role of Hydrotalcite as a Catalyst
  • 2.1.1. Base Catalysis
  • 2.1.2. Redox Catalysis
  • 2.1.3. Acid-Base Tandem Catalysis
  • 2.1.4. Selectivity Enhancement
  • 2.1.5. Stability and Recyclability
  • 2.1.6. Environmental Remediation
  • 2.1.7. Green Chemistry Applications
  • 2.1.8. Solid Base Catalyst
  • 2.2. Heterogeneous Catalysis
  • 2.3. Applications in Petrochemical Industry
  • 2.3.1. Heat stabilizers in Polyvinyl Chloride (PVC) Production
  • 2.3.2. Halogen Scavengers in Polypropylene Production
  • 2.3.3. Fillers in Plastics
  • 2.3.4. Catalyst Supports
  • 2.3.5. Sorbents