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Molecular Physics. Theoretical Principles and Experimental Methods

  • Book

  • 500 Pages
  • December 2018
  • John Wiley and Sons Ltd
  • ID: 2936153
The richly illustrated, advanced textbook comprehensively explains the important principles of diatomic and polyatomic molecules and their spectra in two distinct parts. The first concentrates on the theoretical aspects of molecular physics, such as the vibration, rotation, electronic states, potential curves, and spectra of molecules, while also covering the different methods of approximation for the calculation of electronic wave functions and their energy. The introduction of basic terms used in group theory and their meaning in molecular physics enables an elegant description of polyatomic molecules and their symmetries. A whole chapter is devoted to molecular spectra and the dynamic processes involved in their excited states. The theoretical section concludes with a discussion of the field of Van der Waals molecules and clusters.
The second part is devoted entirely to experimental techniques, such as laser, Fourier, NMR, and ESR spectroscopies, used in the fields of physics, chemistry, biology, and material science. Time–resolved measurements and the influence of chemical reactions by coherent controls are also treated, and a list of general textbooks and specialized literature is provided for further reading.
With its specific examples, definitions, and integrated notes to aid understanding, this textbook is suitable for undergraduates and graduates in physics and chemistry with a knowledge of atomic physics and who are familiar with the basics of quantum mechanics.

Table of Contents

1. Introduction
2. Electronic States of Molecules
3. Rotation, Vibration and Potential Curves of Diatomic Molecules
4. The Spectra of Diatomic Molecules
5. Molecule Symmetries and Group Theory
6. Rotation and Vibrations of Polyatomic Molecules
7. Electronic States of Polyatomic Molecules
8. The Spectra of Polyatomic Molecules
9. Collapse of the Born–Oppenheimer–Approximation, Perturbations in Molecular Spectra
10. Molecules in external Fields
11. Van–der–Waals–Molecules and Cluster
12 Infrared Spectroscopy of Molecules
13 Visible and UV Spectroscopy
14 Laser Spectroscopic Techniques
15 Time resolved Spectroscopy
16 Spectroscopy of Biological Molecules
17 Molecular Physics in Astronomy

Authors

Wolfgang Demtröder