A comprehensive compilation of the available experimental and theoretical vibrational data for organometallic compounds and its role in evaluating the structures, bonding, and properties of these key compounds
This unique book offers a thorough review of the literature dealing with vibrational data obtained using various phases, including matrices, reported for organometallic compounds from infrared spectra, Raman spectra, and several other techniques. It is the only one that compiles the available experimental and theoretical vibrational data on these compounds, and which discusses the importance of this information and its role in evaluating structures, bonding, and other important properties. It also treats the use of DFT and other theoretical calculations to analyze the vibrational data and to predict properties associated with these compounds. The book also includes vibrational data for organic species that form on metal and other surfaces.
Vibrational Spectra of Organometallics: Theoretical and Experimental Data offers complete coverage of: Carbide, Alkylidyne, Alkylidene, Alkyl, and Alkane Derivatives; Noncyclic Carbon Clusters and Unsaturated Hydrocarbon Derivatives; and Cyclic, Unsaturated Organometallic Derivatives. By summarizing work that has already been done on organometallic compounds, it serves as an important reference for those studying their vibrational spectra and will, in the end, lead to a clearer understanding of other research that needs to be done in order to help researchers determine new research directions.
- An important reference for those studying the vibrational spectra of organometallic compounds
- Gathers the existing experimental and theoretical vibrational data and discusses its significance in assessing structures, bonding, and other principle properties
- Includes DFT methods for the interpretation of spectra, which has been one of the major developments of the last two decades
Vibrational Spectra of Organometallics: Theoretical and Experimental Data is an important reference for researchers and practitioners in the areas of inorganic, organometallic, organic, and surface chemistry who have an interest in using vibrational data to characterize the bonding, composition, reactions, and structures of organometallic compounds, and organic species that are formed on various surfaces.
Table of Contents
Preface xi
Part I Carbide, Alkylidyne, Alkylidene, Alkyl, and Alkane Compounds 1
1 Monocarbide Complexes 3
2 Terminal and Bridging Methylidyne (CH) and Other Alkylidyne Complexes 9
3 Terminal and Bridging Methylidene (CH2) and Other Alkylidene Complexes 13
4 Methyl Complexes 21
4.1 Neutral Monomeric Complexes 21
4.2 Cationic and Anionic Monomeric Complexes 29
4.3 Bridged Methyl Complexes 33
5 Methane and Other Alkane Complexes 37
6 Terminal and Bridged Ethyl Complexes 43
7 Propyl, Butyl, and Pentyl Complexes 49
8 Cycloalkyl and Cycloalkane Complexes 53
9 Saturated Heterometallacycle Complexes 55
10 Benzyl Complexes 59
11 Mixed Alkyl and Alkyl-Aryl Complexes 61
12 Surface Bound Alkyl, Alkane, and Alkyl-Metal Complexes 63
12.1 Metal Surfaces 63
12.2 Metalloid Surfaces 65
12.3 Inorganic Oxide Surfaces 66
13 Alkyl, Alkylidyne, and Alkylidene Complexes with Other Functional Groups 69
13.1 Hydrides 69
13.2 Halides and Mixed Halides and Hydrides 84
13.3 Pseudohalides 120
13.4 Carbonyl and Dinitrogen Complexes 135
13.5 Diazomethane (CH2N+=N−) and Related Complexes 139
13.6 Organic Isocyanides (Isonitriles, R‐N≡C), Organic Nitriles (R‐C≡N) and Iminoacyl Complexes 139
13.7 Carbon Dioxide and Carbon Disulfide Complexes 141
13.8 Aqua, Hydroxide, Oxide, Peroxide, and Oxyhalide Complexes 146
13.9 Hydrogen Sulfide, Mercaptide, Sulfide, and Disulfide Complexes 161
13.10 Alkoxide, Organoperoxide, Ether, and Alcohol Complexes 164
13.11 Alkylsulfide, Dialkylsulfide, and Methanethiol Complexes 171
13.12 Carboxylate, Thiocarboxylate, Dithiocarboxylate, and Xanthate Complexes 173
13.13 Formaldehyde, Formyl, Acetaldehyde, Acyl, and Related Complexes 180
13.14 Ketone, Ketenyl, and Related Complexes 187
13.15 β‐Diketonate and Related Complexes 190
13.16 Nitrogen Bases and Miscellaneous Lewis‐Base and Chelating Ligands 195
14 Complexes with Metal-Metal Bonds 215
14.1 Homonuclear Bonds 215
14.2 Heteronuclear Bonds 219
15 Halogenated Alkyl Complexes 225
15.1 Main Group Elements 225
15.2 Transition and Actinide Elements 234
Part I References 241
Part II Noncyclic Carbon-Clusters and Unsaturated Hydrocarbon Compounds 299
16 Linear Carbon Cluster Complexes 301
16.1 C2 Complexes 301
16.2 C3 Complexes 304
16.3 C4 Complexes 304
16.4 C5 and Larger Complexes 305
17 Ethynyl, Ethyne, and Related Complexes 309
17.1 Main Group Elements 309
17.2 d and f Block Elements 319
18 Vinyl and Vinylidene Complexes 343
19 Ethene and Related Monoalkene Complexes 355
20 Allyl and Related Complexes 371
21 Allene and Related Complexes 387
22 Conjugated and Nonconjugated Diolefin and Related Complexes 391
22.1 Butadiene and Butatriene Complexes 391
22.2 Pentadiene Complexes 396
22.3 Hexadiene Complexes 398
22.4 Miscellaneous Olefin Complexes 399
Part II References 403
Part III Cyclic, Unsaturated Organometallic Compounds 427
23 Metal Complexes of Fullerenes and Other Nonlinear Carbon Clusters 429
24 Three‐carbon Rings 433
25 Four‐carbon Rings 435
26 Five‐carbon Rings 441
26.1 Cyclopentene and Cyclopentyl Complexes 441
26.2 1,3‐Cyclopentadiene, Cyclopentadienone, and Related Complexes 441
26.3 Anionic Cyclopentadienide Complexes 443
26.4 Covalent Cyclopentadienyl Complexes 446
27 Six‐carbon Rings 547
27.1 Cyclohexene Complexes 547
27.2 Cyclohexadiene, Cyclohexadienyl, Oxocyclohexadienyl, and Quinone Complexes 547
27.3 Neutral, Cationic, and Anionic Phenyl Complexes 550
27.4 Phenyl Compounds with Other Functional Groups 559
27.5 Phenyl Complexes with Metal-Metal Bonds 585
27.6 Ring‐Substituted Phenyl Complexes 588
27.7 Perhalogenated Phenyl Complexes 591
27.8 Benzene Ring Complexes 596
27.9 Ring‐Substituted Benzene Complexes 608
27.10 Benzyne Complexes 611
28 Seven‐carbon Rings 613
29 Eight‐carbon Rings 615
30 Nine‐carbon Rings 629
31 Ten‐carbon Rings 631
32 Coupled Organic Ring Complexes 633
33 Fused Organic Ring Complexes 635
33.1 Pentalenyl Complexes 635
33.2 Indene and Indenyl Complexes 635
33.3 Fluorene and Fluorenyl Complexes 641
33.4 Indacenyl Complexes 641
33.5 Azulene Complexes 641
33.6 Naphthalene and Larger Fused Aromatic Ring Complexes 642
34 Miscellaneous Cyclic Olefin and Mixed Ring Complexes 643
35 Carboranes and Metallacarboranes 647
36 Five‐ and Six‐membered Heterocyclic Rings and Their Metal Complexes 651
37 Unsaturated Metallacycle Rings with Four or More Atoms 657
Part III References 661
Index 709
