Heterogeneous Catalysis in Sustainable Synthesis is a practical guide to the use of solid catalysts in synthetic chemistry that focuses on environmentally benign applications. Collating essential information on solid catalysts into a single volume, it reveals how the efficient use of heterogeneous catalysts in synthetic chemistry can support sustainable applications. Beginning with a review of the fundamentals of heterogeneous catalytic synthesis, the book then explores the basic concepts of heterogeneous catalytic reactions from adsorption to catalyst poisons, the use of non-traditional activation methods, recommended solvents, the major types of both metal and non-metal solid catalysts, and applications of these catalysts in sustainable synthesis.
Based on the extensive experience of its expert author, this book aims to encourage and support synthetic chemists in using solid catalysts in their own work, while also highlighting the important link between heterogeneous catalysis and sustainability to all those interested.
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Table of Contents
1. Heterogeneous catalysis for organic synthesis: historical background and fundamentals2. Solid catalysts for environmentally benign synthesis
3. Application of heterogeneous catalysis in the development of environmentally benign synthetic processes
3.1. Hydrogenation
3.2. Heterogeneous catalytic hydrogenolysis of organic compounds
3.3. Heterogeneous catalytic oxidations
3.4. Metathesis by heterogeneous catalysts
3.5. Friedel-Crafts and related reactions catalyzed by solid acids
3.6. Cross-coupling reactions for environmentally benign synthesis
3.7. Multicomponent Reactions
3.8. Ring transformations by heterogeneous catalysis
3.9. Heterogenous catalytic rearrangements and other transformations
3.10. Asymmetric synthesis by solid catalysts