Discover the relationships between inorganic chemical synthesis, structure, and property with these comprehensive and insightful volumes
Advanced Structural Chemistry: Tailoring Properties of Inorganic Materials and their Applications (3 Volume Set) offers readers the opportunity to discover the relationship between the structure and function of matter, develop efficient and precise synthesis methodology, and to understand the theoretical tools for new functional substances.
Advanced Structural Chemistry clarifies the relationships between synthesis and structure, as well as structure and property, both of which are central to the creation of new materials with unique functions. In addition to subjects like the syntheses of metal-oxide clusters, metal-organic cages, and metal-organic frameworks with tailored optical, electric, ferroelectric, magnetic, adsorption, separation, and catalytic properties, the accomplished editor Rong Cao provides readers with information on a wide variety of topics, such as:- Coordination-assembled metal-organic macrocycles and cages, including metallacycles and metallacages- The structural chemistry of metal-oxo clusters, including the oxo clusters of transition metal, main group metal, and lanthanides- Synthetic approaches, structural diversities, and biological aspects of molybdenum-based heterometallic sulfide clusters and coordination polymers- Group 11-15 metal chalcogenides, including discrete chalcogenide clusters synthesized in ionic liquids- The structures of metal-organic frameworks, including one-, two-, and three-dimensional MOFs
Perfect for inorganic chemists, structural chemists, solid state chemists, material scientists, and solid state physicists, Advanced Structural Chemistry also belongs on the bookshelves of catalytic and industrial chemists who seek to improve their understanding of the structure and functions of inorganic materials.
Table of Contents
Volume 1
1 Introduction 1
Jian Zhang, Guo-Cong Guo, Rong Cao, and Xin-Tao Wu
2 Coordination-Assembled Metal-Organic Macrocycles and Cages 9
Xiao-Zhen Li, Yu-Ling Liang, Li-Peng Zhou, Li-Xuan Cai, Qiang-Yu Zhu, Zhuo Wang, Xiao-Qing Guo, Dan-Ni Yan, Shao-Jun Hu, Shao-Chuan Li, Shi-Yu Wu, Shi-Long Han, Ran Chen, Pei-Ming Cheng, Kai Cheng, Xiao-Shan Feng, Tian-Pu Sheng, Can He, Feng-Rong Dai, and Qing-Fu Sun
2.1 Introduction 9
2.2 Metallacycles 9
2.2.1 Dinuclear Metallamacrocycles 10
2.2.2 Triangles 10
2.2.3 Rectangle 12
2.2.4 Hexagons 14
2.2.5 Irregular Metallacycles 20
2.2.6 Multilayered Metallacycles 22
2.2.7 Polygon-Based Polymers 28
2.2.8 Responsive Dynamic Metallacycles 34
2.3 Metallacages 35
2.3.1 Helicates 35
2.3.2 Tetrahedron 38
2.3.3 Truncated Tetrahedron 46
2.3.4 Triangular Prism 47
2.3.5 Cubes 50
2.3.6 Octahedron 54
2.3.7 Dodecahedron 61
2.3.8 Cuboctahedrons 65
2.3.9 Hexadecahedrons 65
2.3.10 Barrel-Shaped Cages 67
2.3.10.1 Calixarene Constructed Barrel-Shaped Cages 67
2.3.10.2 Dimetallic Clips-Constructed Barrel-Shaped Cages 68
2.3.11 Multiple Structural Cages 71
2.3.12 Other Cages 74
2.4 Conclusion 77
Acknowledgments 77
References 77
3 Structural Chemistry of Metal-Oxo Clusters 81
Xiaofeng Yi, Weihui Fang, Jinying Liu, Cheng Chen, Mingyan Wu, and Lei Zhang
3.1 Oxo Clusters of Transition Metal 81
3.1.1 Introduction 81
3.1.2 General Synthetic Approaches and Experimental Methods 83
3.1.2.1 General Synthetic Approaches 83
3.1.2.2 Experimental Methods 83
3.1.3 Polyoxotitanates (POTis) 84
3.1.3.1 Diverse Structures of POTis 84
3.1.3.2 Tuneable Properties of POTis: Bandgap Engineering and Photo-Related Activities 89
3.1.3.3 Potential Application of POTis 92
3.1.4 Polyoxovanadates (POVs) 95
3.1.4.1 Diverse Structure of POVs 95
3.1.4.2 Tunable Properties and Potential Applications of POVs 101
3.1.5 Polyoxoniobates (PONbs) 102
3.1.6 Polyoxomolybdates (POMos) 104
3.1.7 Polyoxopalladates (POPs) 105
3.1.8 Polyoxotungstates (POTs) 107
3.1.8.1 Transition-Metals-Substituted-POTs (TMSPs) 107
3.1.8.2 Inorganic-Organic Hybrid TMSPs 107
3.1.9 Polyoxotantalates (POTas) 109
3.2 Oxo Clusters of Main Group Metal 111
3.2.1 Introduction 111
3.2.2 Synthesis of Borates 111
3.2.2.1 Inorganic Templated Borates 112
3.2.2.2 Organic-Templated Borates 113
3.2.2.3 TMC-Templated Borates 113
3.2.2.4 Templated Synthesis of Aluminoborates 115
3.2.3 Synthesis of Germinates and Borogermanates 116
3.2.3.1 Templated Synthesis of Germinates 116
3.2.3.2 Templated Synthesis of Germinates 117
3.2.3.3 Self-Polymerization and Induced Congregation of Lanthanide Germanate Lusters 118
3.2.4 Aluminum Oxo Clusters Hydrolysis and Condensation 119
3.2.4.1 Aluminum Oxo Clusters Isolated from Organic Solutions 119
3.2.4.2 Aluminum Oxo Clusters Via Aqueous Synthetic Routes 120
3.3 Oxo Clusters of Lanthanides 122
3.3.1 Introduction 122
3.3.2 High-Nuclearity Clusters of Lanthanides 123
3.3.2.1 High-Nuclearity Lanthanide Clusters Supported by O-Donor Ligands 123
3.3.2.2 High-Nuclearity Lanthanide Clusters Supported by N-Donor Ligands 127
3.3.2.3 High-Nuclearity Lanthanide Clusters Supported by Multiple N,O-Donor Ligands 129
3.3.2.4 High-Nuclearity Lanthanide Clusters Supported by Calix[n]arenes Ligands 136
3.3.2.5 High-Nuclearity Lanthanide Clusters Supported by Other Donor Ligands 139
3.3.3 Monometallic Lanthanide-Based Single-Molecule Magnets 140
3.3.4 Heterometallic 3d-4f Clusters 142
3.4 Conclusion 149
Acknowledgments 149
References 149
4 Synthetic Approaches, Structural Diversities, and Biological Aspects of Molybdenum (Tungsten)-Based Heterometallic Sulfide Clusters and Coordination Polymers 163
Du Shaowu and Wu Xintao
4.1 Introduction 163
4.2 Synthesis of Mo-Fe-S Cuboidal Clusters for the Structural Modeling of the Iron-Molybdenum Cofactor
(FeMoco) 167
4.3 Rationally Designed Synthesis of Mo(W)-Cu(Ag)-S Clusters 173
4.3.1 Unit Construction Method for the Synthesis of Simple Mo(W)-Cu(Ag)-S Clusters Starting from Thiomolybdates or Thiotungstates Building Units 173
4.3.2 Unit Construction Method for the Synthesis of Single Cubane- and Cage-like Mo(W)-Cu(Ag)-S Clusters Starting from Tri- and Dinuclear Thiomolybdates and Thiotungstates 175
4.3.3 Unit Construction Method for the Synthesis of Mo(W)-Cu(Ag)-S Clusters Having Multiple Cubane-like Structures 178
4.4 Rationally Designed Synthesis of W(Mo)-Ag-S Coordination Polymers 182
4.5 Conclusion 190
Acknowledgments 191
References 191
5 Group 11-15 Metal Chalcogenides 195
Jian-Rong Li, Mei-Ling Feng, Bing Hu, and Xiao-Ying Huang
5.1 Introduction 195
5.2 Inorganic-Organic Hybrid Chalcogenides Based on II-VI Semiconductors 198
5.3 Discrete Chalcogenide Clusters Synthesized in Ionic Liquids 209
5.3.1 Discrete Chalcogenido Tn Clusters 209
5.3.2 Other Discrete Chalcogenide Clusters 21
5.4 Chalcogenidostannates 218
5.4.1 Chalcogenidostannates 219
5.4.2 Heterometallic Chalcogenidostannates Containing Ag+ 228
5.5 Chalcogenidoantimonates 234
5.5.1 Thioantimonates 234
5.5.2 Chalcogenidometalates Containing Group 12(II) Ions and Antimony(III) 236
5.5.3 Chalcogenidometalates Containing Group 13(III) Ins and Antimony(III) 245
5.5.3.1 Ga-Sb-S Compounds 246
5.5.3.2 In-Sb-Q (Q = S and Se) Compounds 248
5.5.4 Chalcogenidometalates Containing Group 14(IV) Ions and Antimony(III) 254
5.5.4.1 Ge-Sb-S Compounds 254
5.5.4.2 Sn-Sb-S Compounds 259
5.6 Selected Properties 260
5.6.1 Properties of Selected Inorganic-Organic Hybrid Metal Chalcogenides 260
5.6.1.1 Optical and Electric Properties 261
5.6.1.2 Thermal Expansion Behavior 263
5.6.2 Photocatalytic Property 264
5.6.2.1 Photocatalytic Hydrogen Production 265
5.6.2.2 Photodegradation of Organic Dye Molecules 267
5.6.3 Ion Exchange Property 269
5.7 Conclusion 275
Acknowledgments 276
References 277
Volume 2
6 The Structures of Metal-Organic Frameworks 283
Yuehong Wen, Xintao Wu, and Qi-Long Zhu
7 Structural Design and Rational Synthesis 391
Qipu Lin
8 Structural Topologies and Interpenetration in the Coordination Polymers 425
Fei Wang, Hai-Xia Zhang, and Jian Zhang
9 Inorganic Chalcogenides: From Zero-Dimensional Clusters to Three-Dimensional Frameworks 465
Hua Lin, Xin-Tao Wu, and Qi-Long Zhu
10 Relationship Between Structure and Electroluminescent, Photochromic, orSecond-Order Nonlinear Optical Property 531
Ming-Sheng Wang, San-Gen Zhao, Qian Wang, and Zhong-Ning Che
11 Relationship Between Structure and Ferroelectric Properties 601
Wuqian Guo, Zhihua Sun, Zhiyun Xu, Shiguo Han, and Junhua Luo
Volume 3
12 The Relationship Between Structure and Electric Property 669
Guan-E Wang, Yonggang Zhen, Guo-Dong Wu, Huanli Dong, and Gang Xu
13 Understanding Magneto-Structural Correlations Toward Design of Molecular Magnets 777
Zhu Zhuo, Guo-Ling Li, and You-Gui Huang
14 Relationship Between MOF Structures and Gas Absorption Properties 833
Qi Yin and Tian-Fu Liu
15 Relationship Between Structure and Separation Property 881
Zhanfeng Ju, El-Sayed M. El-Sayed, and Daqiang Yuan
16 Catalysis in Metal-Organic Frameworks: Relationship Between Activities and Structures 953
Yuan-Biao Huang, Teng Zhang, and Rong Cao
Index 995
