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Handbook of Ionic Liquids. Fundamentals, Applications and Sustainability. Edition No. 1

  • Book

  • 528 Pages
  • March 2024
  • John Wiley and Sons Ltd
  • ID: 5863891
Handbook of Ionic Liquids

A one-stop reference for researchers interested in ionic liquids and their applications

Handbook of Ionic Liquids: Fundamentals, Applications, and Sustainability, constitutes an overview of the latest advances in ionic liquid chemistry. It offers a comprehensive summary of the development history of ionic liquids, their design, and the diverse array of applications - including green and sustainable synthesis, catalysis, drug development and medicine, biotechnology, materials science, and electrochemistry.

The authors explain a variety of processes used to develop novel materials with ionic liquids and describe likely future developments using practical examples taken from contemporary research and development in the field. The book includes discussions of biomass conversion, CO2 capture, and more. You’ll also discover: - A thorough introduction to the theory of ionic liquids, as well as their different types and recycling methods - Comprehensive explorations of the physico-chemical properties of ionic liquids - Practical discussions of ionic liquid synthesis and analysis, including green synthesis and heterocyclic chemistry applications - Summary of the use of ionic liquids in materials science, including polymers, energy conversion, and storage devices

Perfect for organic, catalytic, physical, analytical, and environmental chemists, Handbook of Ionic Liquids: Fundamentals, Applications, and Sustainability will also benefit electrochemists, materials scientists, and biotechnologists with an interest in ionic liquids and their application.

Table of Contents

Preface xvii

1 History and Development of Ionic Liquids 1
Sumana Brahma and Ramesh L. Gardas

1.1 Introduction 1

1.2 Constituents of ILs 2

1.3 The Brief History 3

1.4 Ionic Liquid-Like Systems 6

1.5 The Generation of ILs 6

1.6 Structural Development of ILs 9

1.7 Scope of ILs 17

1.8 Commercialization of ILs 18

1.9 Conclusions 20

2 Growth of Ionic Liquids and their Applications 29
Sudakhina Saikia, Himadri Borah, Pangkita Deka, and Rekha R. Dutta

2.1 Introduction 29

2.2 Growth of Ionic Liquids 30

2.3 Applications of Ionic Liquids 33

2.4 Conclusion and Future Prospects 44

3 Study of Physicochemical Properties of Ionic Liquids 51
Tridib Mondal and Palas Samanta

3.1 Introduction 51

3.2 Physicochemical Properties of Ionic Liquids 52

3.3 Conclusion and Perspectives 62

4 Ionic Liquids as Green Solvents: Are Ionic Liquids Nontoxic and Biodegradable? 69
Helen Treasa Mathew, Kumar Abhisek, Shashikant Shivaji Vhatkar, Arvind Kumar, and Ramesh Oraon

4.1 Introduction 69

4.2 Toxicity and Biodegradability of Ionic Liquids 71

4.3 Applications of Ionic Liquids as Green Solvents 78

4.4 IoNanofluids 82

4.5 Conclusion 88

5 Promising Uses of Ionic Liquids on Carbon - Carbon and Carbon - Nitrogen Bond Formations 97
Sudeshna Kalita and Anup Singhania

5.1 Introduction 97

5.2 Carbon - Carbon Bond Formation Reactions 98

5.3 Carbon - Nitrogen Bond Formation Reaction 117

5.4 Conclusion 131

6 Ionic Liquids in Separation Techniques 141
Hailu Demissie, Fidelis O. Ajibade, Eden Mulu, Jean J.R. Kinhoun, Temitope F. Ajibade, Kayode H. Lasisi, Nathaniel A. Nwogwu, and Daniel A. Ayejoto

6.1 Introduction 141

6.2 General Characteristics of ILs 143

6.3 The Use of ILs in Separation Technology 145

6.4 Conclusions and Future Perspectives 153

7 Polymers and Ionic Liquids 161
Hailu Demissie, Fidelis O. Ajibade, Jean J. R. Kinhoun, Eden Mulu, Temitope F. Ajibade, Ehiaghe A. Elimian, Bashir Adelodun, Pankaj Kumar, and Oluwaseyi A. Ajala

7.1 Introduction 161

7.2 Properties of ILs 163

7.3 Synthesis of PILs 166

7.4 Types and Application of Common PILs 167

7.5 Conclusion 167

8 Effect of Ionic Liquids on Electrochemical Biosensors and Other Bioelectrochemical Devices 179
Himadri Borah, Upakul Dutta, and Rekha R. Dutta

8.1 Introduction 179

8.2 The Importance of Ionic Liquids in Electrochemistry 181

8.3 Fabrication of IL-Based Sensing Layers 184

8.4 IL-Based Electrochemical Biosensors 186

8.5 Application of Ionic Liquids in Bioelectrochemical Devices 191

8.6 Conclusions and Future Prospects 191

9 Nanopharmaceuticals With Ionic Liquids: A Novel Approach 195
Bharadwaj Ittishree, Lipeeka Rout, Vinod Kashyap, and Rahul Sharma

9.1 Introduction 195

9.2 Applications of Ionic Liquids in Various Fields 196

9.3 Nanotechnology and Ionic Liquids 197

9.4 Use of Ionic Liquids in Nanocarrier Development (ReportedWork) 198

9.5 Ionic Liquid-Assisted Metal Nanoparticles 198

9.6 Conclusion 201

10 Anticancer Activity of Ionic Liquids 203
Atrayee Banaspati and Nirupamjit Sarmah

10.1 Introduction 203

10.2 Classification of Ionic Liquids 205

10.3 Toxicity of Ionic Liquids 207

10.4 Anticancer Potential of Ionic Liquids 209

10.5 Conclusions and Future Scope 213

11 Importance of Ionic Liquids in Plant Defense: A Novel Approach 221
Mamun Mandal and Abhijit Sarkar

11.1 Introduction 221

11.2 Generation of ILs and Their Application 222

11.3 Role of ILs in Plant Defense Mechanisms 224

11.4 IL Products in Future Management of Agri Industries: An Innovative Approach 229

11.5 Conclusions 230

12 Theoretical Description of Ionic Liquids 235
Daniel A. Ayetoro, Nathaniel A. Nwogwu, Kelechi E. Igwe, Ehiaghe A. Elimian, Hailu Demissie, Temitope F. Ajibade, Abdulhamid Yusuf, Kayode H. Lasisi, Pankaj Kumar, Bashir Adelodun, and Fidelis O. Ajibade

12.1 Introduction 235

12.2 Ionic Liquid Dynamics 237

12.3 Theoretical Advances in Force Fields and Electronic Structures 239

12.4 Mixtures in Ionic Liquids 241

12.5 Applications of Ionic Liquids in Chemical Processes 245

12.6 Future Developments 247

12.7 Conclusion 248

13 Theoretical Understanding of Ionic Liquid Advancements in the Field of Medicine 255
Mrinal K. Si

13.1 Introduction 255

13.2 A Brief History of Ionic Liquids and Deep Eutectic Solvents 257

13.3 Biomedical Applications 257

13.4 Summary and Future Aspects 260

14 Recent Developments in Ionic Liquid Research from Environmental Perspectives 265
Prarthana Bora and Swapnali Hazarika

14.1 Introduction 265

14.2 Applications of Ionic Liquids 267

14.3 Limitations of Ionic Liquids 278

14.4 Conclusion 279

15 Ionic Liquids for Sustainable Biomass Conversion in Biorefinery 283
Rakesh Dutta and Khemnath Patir

15.1 Introduction 283

15.2 Biomass as a Source of Organic Compounds and Fuels 284

15.3 Biomass Conversion Process 285

15.4 Value-Added Organic Compounds from Biomass in Ionic Liquids 286

15.5 Production of Biodiesel with Ionic Liquids 291

15.6 Toxicity and Ecotoxicity of ILs for Biorefinery 292

15.7 Conclusions 295

16 Ionic Liquids for Atmospheric CO2 Capture: A Techno-Economic Assessment 301
Kumar Abhisek, Helen T. Mathew, Shashikant S. Vhatkar, Dipti S. Srivastava, Rahul Minz, and Ramesh Oraon

16.1 Introduction 301

16.2 Different Processes of CO2 Capture 303

16.3 Conclusion 316

17 Recovery of Biobutanol Using Ionic Liquids 333
Kalyani Motghare, Diwakar Shende, Dharam Pal, and Kailas L. Wasewar

17.1 Introduction 333

17.2 Biobutanol: First-Generation Biofuels 335

17.3 Butanol Production 335

17.4 Butanol Recovery 337

17.5 Ionic Liquids 339

17.6 Recovery of Biobutanol Using Ionic Liquids 343

17.7 World Butanol Demand 344

17.8 Conclusion 345

18 Bio-Carboxylic Acid Separation by Ionic Liquids 353
Anuj Kumar, F.M. Antony, D.Z. Shende, and K.L. Wasewar

18.1 Introduction 353

18.2 Ionic Liquids 355

18.3 Challenges in the Separation of Bio-Carboxylic Acids 357

18.4 Methods for Separating Bio-Carboxylic Acids 357

18.5 Separation of Bio-Carboxylic Acids by the Reactive Extraction Process 360

18.6 Conclusion and Perspectives 364

19 Current Trends in QSAR and Machine Learning Models of Ionic Liquids: Efficient Tools for Designing Environmentally Safe Solvents for the Future 369
Supratik Kar and Jerzy Leszczynski

19.1 Ionic Liquids and Their Structural Characteristics 369

19.2 Properties of ILs 372

19.3 Application of ILs 372

19.4 Do ILs Follow Green Chemistry Principles and Are Hazard Free for Environment? 375

19.5 Regulatory Proposals for Toxicity Assessment of ILs 376

19.6 Why In Silico Modeling Is Needed for ILs 377

19.7 Predictive Toxicity Models for ILs 378

19.8 Databases of Ionic Liquid 380

19.9 Overview and Future Avenues 388

20 Advances in Simulation Research on Ionic Liquid Electrolytes 395
Huo Feng and Yue Bowen

20.1 Simulation Method of Ionic Liquid Electrolytes 396

20.2 Advances in Simulation of Ionic Liquid Electrolytes in Batteries 403

20.3 Advances in Simulation of Ionic Liquid Electrolytes in Capacitors 408

20.4 Conclusion 413

21 Applications of Ionic Liquids in Heterocyclic Chemistry 419
Suresh Rajamanickam and Binoyargha Dam

21.1 Introduction 419

21.2 Application of Ionic Liquids in the Syntheses of Various Heterocycles 421

21.3 Conclusion and Future Prospective 440

22 Application of Ionic Liquids in Drug Development 443
Partha Dutta, Charu Arora, and Sanju Soni

22.1 Introduction 443

22.2 Classification of Ionic Liquids 444

22.3 General Synthetic Methodologies 444

22.4 An Overview of Applications in Diverse Fields 445

22.5 Specific Applications in the Field of Pharmaceutical Development 447

23 Application of Ionic Liquids in Biocatalysis and Biotechnology 459
Ehiaghe Agbovhimen Elimian, Fidelis Odedishemi Ajibade, Temitope Fausat Ajibade, Hailu Demissie, Nathaniel Azubuike Nwogwu, Kayode Hassan Lasisi, Daniel A. Ayetoro, and Ehizonomhen Solomon Okonofua

23.1 Introduction 460

23.2 Properties of Ionic Liquids 460

23.3 Whole-Cell Biotransformations 464

23.4 Ionic Liquids as Solvents for Enzyme Catalysis 467

23.5 Enzyme Selectivity in Ionic Liquids 469

23.6 Ionic Liquid Stability of Enzymes 470

23.7 Application of Ionic Liquids in Bioethanol Production 471

23.8 Ionic Liquids Applied in the Synthesis of Biodiesel 475

23.9 Conclusion 479

References 479

Index 489

Authors

Sanchayita Rajkhowa Haflong Government College. Pardeep Singh University of Delhi, New Delhi, India. Anik Sen GITAM. Jyotirmoy Sarma Assam Don Bosco University.