Electrochemical Energy Storage Technologies Beyond Li-ion Batteries: Fundamentals, Materials, Devices focuses on an overview of the current research directions to enable the commercial translation of electrochemical energy storage technologies. The principles of energy storage mechanisms and device design considerations are introduced, along with advances in candidate materials and their path to commercialization and industrialization. Electrochemical energy storage technologies reviewed include rocking chair batteries, metal-air batteries, redox flow batteries, fuel cells, and supercapacitors. This book is suitable for materials scientists and chemists in academia and industry. It may also be of interest to physicists and energy scientists and practitioners.
Table of Contents
PART 1 Fundamentals of electrochemical energy storage technologies1. Fundamental electrochemical energy storage mechanisms
1 Overview
2 Electron transfer and mass transport
3 Electrochemistry of electrolyte
4 Electrochemistry of electrode
5 Interface
2. Configurations of electrochemical energy storage devices
1 Overview
2 Device configuration design principles
3 Redox flow batteries (RFBs)
4 The function of separators
3. Material characterization and electrochemical test
techniques
1 Introduction
2 Basic characterization and electrochemical test techniques
3 Advanced characterization and electrochemical test techniques
4 Conclusion
4. Selected quantum chemical studies on the surfaces and interfaces of carbon materials for applications in lithium-ion
batteries and beyond
1 Introduction
2 A brief introduction to density functional theory (DFT)
3 The interaction of Li, Na, and K with carbon materials
4 Concluding remarks and perspectives
PART 2 Non-lithium-ion rocking chair batteries: Candidate materials and device design considerations
5. Sodium-ion batteries
1 Introduction
2 Anode materials
3 Electrolytes for NIBs
4 Separators and current collectors for NIBs
5 Cathode materials
6 Conclusions
6. Potassium-ion batteries: Mechanism, design,
and perspectives
1 Introduction
2 Anode materials
3 Cathode materials
4 Electrolytes
5 Binders
6 Conclusion and perspectives
7. Zinc-ion batteries: Recent trends in zinc-ion batteries
1 Introduction
2 Materials used in zinc-ion batteries
8. Rechargeable magnesium-ion batteries: From mechanism
to emerging materials
1 Introduction
2 Working mechanism and main challenges
3 Cathode
4 Anode
5 Electrolyte
6 Summary and outlooks
9. Aluminum-ion batteries
1 Introduction of rechargeable aluminum-ion batteries
2 Cathode materials
3 Electrolytes
4 Al metal anode and related technologies
5 Other materials
6 Conclusion and perspectives
10. Calcium-ion batteries
1 A general introduction to this technology
2 Challenges in developing modern CIBs
3 Anode materials
4 Cathode
5 Perspectives
11. Materials electrochemistry for dual-ion batteries
1 Understanding of dual-ion batteries
2 Positive electrode design
3 Negative electrode design
4 Electrolyte design
5 Conclusion and perspectives
PART 3 Emerging metal-air batteries and fuel cells: Candidate materials and device design considerations
12. Lithium-air batteries
1 Introduction
2 Anode materials
3 Air-cathode materials
4 Electrolytes
5 Other components
6 Conclusion and future perspectives
13. Zinc-air batteries
1 A general introduction to this technology
2 Zn anode-related technologies
3 Air-cathode materials
4 Electrolytes
5 Other components (binder, current collector, separator, etc.)
6 Conclusion and perspectives
14. Solid oxide fuel cells (SOFCs)
1 Introduction
2 Electrolyte materials
3 SOFC electrode materials
4 Other components (interconnect)
5 Electrocatalysts
6 Commercialization and industrialization of SOFCs
7 Conclusions
PART 4 Redox flow batteries: Candidate materials and device design considerations
15. All-vanadium redox flow batteries
1 Topic 1: A general introduction to this technology
2 Topic 2: Electrolyte materials
3 Topic 3: Membrane materials
4 Topic 4: Electrodes
5 Topic 5 Summary and perspective
16. Zinc-based hybrid flow batteries
1 Overview
2 Introduction
3 Different types and configurations of ZHFBs
4 Other components of ZHFBs
5 Conclusions and outlook
PART 5 Supercapacitors: Candidate materials and device design considerations
17. Electrochemical double layer capacitors (EDLCs)
1 Electric double layer (EDL)
2 Application of double electric layer
18. Pseudocapacitors
1 Overview
2 Pseudocapacitive energy storage mechanisms
3 Kinetic analysis
4 Device structure
5 Performance evaluation
6 Pseudocapacitive materials
7 Pseudocapacitive electrolytes
8 Conclusion and perspectives
19. Exploring hybrid capacitors: Advanced concepts and applications
1 Introduction
2 Different HCs and the anode and cathode materials
3 Electrolytes
4 Binders
5 Separator
6 Current collector
7 Conclusion
PART 6 Future outlooks and challenges
20. Challenges and future prospective of nonlithium electrochemical energy storage technologies
1 Overview
2 Challenges in practical application of nonlithium technologies
3 Strategies for overcoming challenges
4 Future prospects and market dynamics